Product ID:1604 SHADOW GRAY,INDUSTRIAL MAINTENANCE (SUPDAT)
MSDS Date:01/05/1994
FSC:8010
NIIN:00N077446
MSDS Number: CDTRY

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44199
US

Emergency Phone: 216-292-7400

Info Phone: 800-247-6266

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 13%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

700

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 7%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

7.1

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 2%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

160

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 35%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 8%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 3%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/75 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYL ETHER ESTER;

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 8%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 3-13.7%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

VOLATILE ORGANIC COMPOUND AS A PERCENT BY WEIGHT PER BAAQMD

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS

RTECS: 9999999ZZ

& PRLNGD OVEREXP TO SOLVS W/PERMANENT BRAIN &

RTECS: 9999999ZZ

INCIN. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W

RTECS: 9999999ZZ

INCIN/EXPOSE TO TEMP >110F. HEAT FROM SUNLIGHT,

RTECS: 9999999ZZ

COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY.

RTECS: 9999999ZZ

DELIB CONCENTRATING & INHALING CONTENTS CAN BE

RTECS: 9999999ZZ

SPRAY MIST. AVOID CONT W/SKIN & EYES. THIS COATING

RTECS: 9999999ZZ

(LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE

RTECS: 9999999ZZ

DRIED FILM.

RTECS: 9999999ZZ

BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM

RTECS: 9999999ZZ

OSHA STANDARDS 1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES, SKIN &
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH. SIGNS
& SYMPTOMS OF OVEREXPOSURE:HEADACHE , DIZZINESS, NAUSEA, & LOSS OF
COORDINATION ARE INDICATIONS OF EXCESS EXPOSURE TO VAPORS/SPRAY
MISTS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:REDNESS AND ITCHING/BURNING SENSATION
MAY INDICATE EYE/EXCESS SKIN EXPOSURE. CHRONIC:PROLONGED
OVEREXPOSURE TO SOLVENT INGREDS MAY CAUSE ADVERSE EFFECTS TO LIVER,
URINARY, BLOOD-FORMING, CARD IOVASCULAR, AND REPRODUCTIVE SYSTEM.
METHYL ETHYL KETONE MAY INCREASE NERVOUS SYSTEM EFFECTS OF OTHER
SOLVENTS. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH WITH
LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. INGEST:GET MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.9%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPKS, &
OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
APPLIC TO HOT SURFS REQS SPEC PRECS. DURING EMER (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS, & OPEN
FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. CONSULT
NFPA CODE. USE APPRVD BONDING & GROUNDING PROC.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE KEEP AREA
VENTILATED-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, &
HEATERS-TURN OFF STOVES, ELEC TOOLS & APPLICANCES, & ANY OTHER
SOURCES OF IGNIT. CONTENTS UNDE R PRESS. DO NOT PUNCTURE, (ING 14)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICLATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN INGRED SECTION. WHEN
SANDING/ABRADING DRIED FI LM, WEAR DUST/MIST RESP APPRVD (ING 20)
Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS
IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO (ING 21)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:& TOUCH UP SPRAY COLORS, FIRE FIGHT PROC:PVNT
PRESS BUILDUP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT.
EXPLO HAZ:CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ. SYMPS
MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF OVEREXP:RATS
EXPOS TO TITANIUM DIOXIDE DUST @ 250 MG

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENT SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 361. WASTE MUST BE TESTED/IGNITABILITY TO DETERM APPLIC
EPA HAZ WASTE NUMBERS. WASTE FROM PROD CONTAINING METHYL ETHYL
KETONE/COPPER MAY RE Q TESTING FOR EXTRACIABILITY. DO NOT (ING 13)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.